Difluoroethane

Your Professional Difluoroethane Manufacturer in China

Jiangsu July Chemical Co.,Ltd is located in Jiangyin city, Wuxi, Jiangsu Province. It owns two industrial-grade gas of Dimethyl Ether& LPG stations, our mainly products include Dimethyl Ether, LPG, Methanol, R152a, R134a, Ethylene glycol and so on.

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Hfa 134a Propellant

 

Brief Introduction to Difluoroethane

Difluoroethane is an organofluorine compound with the chemical formula C2H4F2. This colorless gas is used as a refrigerant, where it is often listed as R-152a (refrigerant-152a) or HFC-152a (hydrofluorocarbon-152a). It is also used as a propellant for aerosol sprays and in gas duster products. As an alternative to chlorofluorocarbons, it has an ozone depletion potential of zero, a lower global warming potential (124) and a shorter atmospheric lifetime (1.4 years). It has many other names (synonyms), including:

●1,1-difluoroethane

●1,1-difluoro

●DFE

●Ethane

●Ethylidene difluoride

●Ethylidene fluoride

●Freon 152a

●HFC-152a

●R-152a

 
Product Specification
 

 

PubChem CID

6368

Molecular weight

66.0500

IUPAC Standard InChI

InChI=1S/C2H4F2/c3-1-2-4/h1-2H2

IUPAC Standard InChIKey

AHFMSNDOYCFEPH-UHFFFAOYSA-N

CAS Registry Number

624-72-6

Molecular Formula

C2H4F2

Density

900 g/L @ 25 °C

Solubility in water

0.54% @ 0 °C

Vapor pressure

536 kPa (4020 mmHg) @ 21.1 °C

510 kPa (5.1 bar) @ 20 °C

Melting point

−117 °C (−179 °F; 156 K)

Boiling point

−24.7 °C (−12.5 °F; 248.5 K)

Odour

Sweetish.

Odour threshold is subjective and inadequate to warn of overexposure.

PH

Not applicable for gases and gas mixtures

 

 
Difluoroethane Chemical Basic Information
 
1

Chemical Properties: liquefied colourless gas under pressure.

 

2

Chemical Properties: Difluoroethane is a liquefied gas and exists as a liquid at room temperature when contained under its own vapor pressure, or as a gas when exposed to room temperature and atmospheric pressure. The liquid is practically odorless and colorless. Difluoroethane is noncorrosive and nonirritating.

 

3

Uses: HFC 152a is a specialty liquified hydrofluorocarbon gas. It is used as an intermediate in the production of fluorinated polymers, as an aerosol propellant in some specialty applications, and as a component in some refrigerant blends.

 

4

Production Methods: Difluoroethane is prepared from ethyne by the addition of hydrogen fluoride in the presence of a suitable catalyst. The difluoroethane formed is purified to remove all traces of water, as well as traces of the starting materials.

 

5

General Description: Difluoroethane is colorless, odorless gas shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. Difluoroethane is easily ignited. Its vapors are heavier than air and a flame can travel back to the source of leak very easily. This leak can be either a liquid or vapor leak. Difluoroethane can asphyxiate by the displacement of air. Under prolonged exposure to fire or heat the containers may rupture violently and rocket.

 

6

Air & Water Reactions: Highly flammable.

 

7

Reactivity Profile: Halogenated aliphatic compounds, such as Difluoroethane, are moderately or very reactive. Reactivity generally decreases with increased degree of substitution of halogen for hydrogen atoms. Low molecular weight haloalkanes are highly flammable and can react with some metals to form dangerous products. Materials in this group are incompatible with strong oxidizing and reducing agents. Also, they are incompatible with many amines, nitrides, azo/diazo compounds, alkali metals, and epoxides. The reaction of aluminum with various halogenated hydrocarbons produces a self-sustaining reaction with sufficient heat to melt aluminum pieces, examples of other halogenated hydrocarbons are fluorotrichloromethane, dichlorodifluoromethane, chlorodifluoromethane, tetrafluoromethane. The vigor of the reaction appears to be dependent on the combined degree of fluorination and the vapor pressure.

 

8

Health Hazard: Inhalation of concentrated gas will cause suffocation. Contact with liquid can damage eyes because of low temperature. Frostbite may result from contact with liquid.

 

9

Pharmaceutical Applications: Difluoroethane, a hydrofluorocarbon (HFC), is an aerosol propellant used in topical pharmaceutical formulations. Difluoroethane may be used as a vehicle for dispersions and emulsions.
Since difluoroethane does not contain chlorine, there are no environmental controls on the use of this material as a propellant, since it does not deplete the ozone layer and is not a greenhouse gas.

 

10

Safety Profile: Mildly toxic by inhalation. Mutation data reported. Narcotic in high concentration. A very dangerous fire hazard when exposed to heat or flame; can react vigorously with oxidzing materials. See also FLUORIDES.

 

Eye Contact
Immediately flush with large amounts of water for at least 15 minutes, lifting upper and lower lids. Remove contact lenses, if worn, while rinsing. Seek medical attention.

 

Skin Contact
Immerse affected part in warm water. Seek medical attention.

 

Inhalation
●Remove the person from exposure.
●Begin rescue breathing (using universal precautions) if breathing has stopped and CPR if heart action has stopped.
●Transfer promptly to a medical facility.
●Medical observation is recommended for 24 to 48 hours after.
overexposure, as pulmonary edema may be delayed.

 

Ingestion
Ingestion is not considered a potential route of exposure.

First Aid
R152a Gas
 
Handling and Storage
 

Safe Use of the Product

 

●The product must be handled in accordance with good industrial hygiene and safety procedures.

●Only experienced and properly instructed persons should handle gases under pressure.

●Consider pressure relief device(s) in gas installations.

●Ensure the complete gas system was (or is regularily) checked for leaks before use.

●Do not smoke while handling product.

●Use only properly specified equipment which is suitable for this product, its supply pressure and temperature. Contact your gas supplier if in doubt.

●Avoid suck back of water, acid and alkalis.

●Assess the risk of poentially explosive atmospheres and the need for explosion-proof equipment.

●Purge air from system before introducing gas.

●Take precautionary measures against static discharge.

●Keep away from ignition sources (including static discharges).

●Consider the use of only non-sparking tools.

●Do not breathe gas.

●Avoid release of product into work area.

●Ensure equipment is adequately earthed.

R600a Gas
R600 Gas

Safe Handling of the Gas Receptacle

 

●Refer to supplier's container handling instructions.

●Do not allow backfeed into the container.

●Protect containers from physical damage; do not drag, roll, slide or drop.

●When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders.

●Leave valve protection caps in place until the container has been secured against either a wall or bench or placed in a container stand and is ready for use.

●If user experiences any difficulty operating valve discontinue use and contact supplier.

●Never attempt to repair or modify container valves or safety relief devices.

●Damaged valves should be reported immediately to the supplier.

●Keep container valve outlets clean and free from contaminants particularly oil and water.

●Replace valve outlet caps or plugs and container caps where supplied as soon as container is disconnected from equipment.

●Close container valve after each use and when empty, even if still connected to equipment.

●Never attempt to transfer gases from one cylinder/container to another.

●Never use direct flame or electrical heating devices to raise the pressure of a container.

●Do not remove or deface labels provided by the supplier for the identification of the content of the container.

●Suck back of water into the container must be prevented.

●Open valve slowly to avoid pressure shock.

Conditions for Safe Storage, Including Any Incompatibility

 

●1,1-Difluoroethane may react violently with OXIDIZING AGENTS (such as PERCHLORATES, PEROXIDES, PERMANGANATES, CHLORATES, NITRATES, CHLORINE, BROMINE and FLUORINE), and forms explosive compounds with BARIUM; SODIUM; POTASSIUM; and other divalent light METALS and METALLIC AZIDES.

●1,1-Difluoroethane is not compatible with powdered ALUMINUM and MAGNESIUM, and their ALLOYS; LIQUID OXYGEN; BRASS; and STEEL.

●Store in tightly closed containers in a cool, well-ventilated area at temperatures below 125o F (52o C).

●Sources of ignition, such as smoking and open flames, are prohibited where 1,1-●ifluoroethane is used, handled, or stored.

●Use only non-sparking tools and equipment, especially when opening and closing containers of 1,1-Difluoroethane.

Commercial Propane
R152a Refrigerant

 

Disposal Consideration

Waste Treatment Methods
●Contact supplier if guidance is required.
●Do not discharge into areas where there is a risk of forming an explosive mixture with air.
●Waste gas should be flared through a suitable burner with flash back arrestor.
●Do not discharge into any place where its accumulation could be dangerous.
●Toxic and corrosive gases formed during combustion should be scrubbed before discharge to atmosphere.
●Ensure that the emission levels from local regulations or operating permits are not exceeded.
●Refer to the EIGA code of practice Doc. 30 "Disposal of Gases", downloadable at http://www. eiga.eu for more guidance on suitable disposal methods.
●Return unused product in original container to supplier.

 

List of Hazardous Waste Codes
●1406 01 *. Chlorofluorocarbons, HCFC, HFC.
●16 05 04*: Gases in pressure containers (including halons) containing hazardous substances.

 

Additional Information
●External treatment and disposal of waste should comply with applicable local and/or national regulations.

Hazards and Protection
 

Storage

Keep in a cool, dry, dark location in a tightly sealed container or cylinder. Keep away from incompatible materials, ignition sources and untrained individuals. Secure and label area. Protect containers/cylinders from physical damage.

 

Handling

All chemicals should be considered hazardous. Avoid direct physical contact. Use appropriate, approved safety equipment. Untrained individuals should not handle this chemical or its container. Handling should occur in a chemical fume hood.

 
 

Protection

Employees should be provided with and required to use impervious clothing, gloves, face shields (8-in minimum), and other appropriate protective clothing necessary to prevent repeated or prolonged skin contact with liquid or solid. Employees should be provided with and required to use dust- and splash-proof safety goggles where liquid or solid may contact the eyes. Wear appropriate eye protection and protective clothing.

 
 

Respirators

Any self-contained breathing apparatus that has a full facepiece and is operated in a pressure-demand or other positive pressure mode. Any supplied-air respirator that has a full facepiece and is operated in pressure-demand or other positive pressure mode in combination with an auxiliary self-contained breathing apparatus operated in pressure-demand or other positive pressure mode. Any appropriate escape-type, self-contained breathing apparatus.

 
 

Small Spills/Leaks

Evacuate area and ventilate. Wear protective equipment. If required, use an inert absrobent. Sweep up and place in an appropriate container for disposal. Wash contaminated surfaces.

 
 

Stability

No data.

 
 

Incompatibilities

Reacts with chemically active metals such as sodium, potassium, beryllium, or with powdered aluminum, zinc, and magnesium.

 
 

Decomposition

When heated to decomposition it emits toxic fumes of flourides and chlorides. Toxic gases and vapors (such as hydrogen chloride, hydrogen fluoride, carbon monoxide) may be released when 1,1,2,2-tetrachloro-1,2-difluoroethane decomposes. Appearance of toxic decomposition products serves as warning of occurrence of thermal decomposition and detection of sharp acrid odor warns of presence.

 
Ultimate FAQ Guide to Difluoroethane
 

Q: Why do people inhale difluoroethane?

A: Inhalants are often abused due to their ability to acutely induce feelings of euphoria. Difluoroethane is a toxic lipophilic hydrocarbon that crosses the blood-brain barrier and inhibits the central nervous system. Studies have shown the cardiac, renal, and respiratory effects it has when abused.

Q: How much difluoroethane is lethal?

A: The decedent's blood was positive for 1,1-difluoroethane (DFE) (52 mcg/mL) and mitragynine (18 ng/mL). Documented deaths associated with DFE abuses have reported in postmortem blood concentrations as low as 29 µg/mL. DFE is an organofluorine compound that is a colorless gas.

Q: Is difluoroethane bad for you?

A: Rapid evaporation of the liquid may cause frostbite. The substance may cause effects on the cardiovascular system. This may result in cardiac disorders. Exposure at high levels could cause unconsciousness.

Q: What chemical gets you high in air duster?

A: Compressed air duster cans currently available in the USA contain highly toxic substances including different hydrofluorocarbons (including tetrafluoroethane and difluoroethane) which exert a psychoactive effect on the central nervous system.

Q: Does difluoroethane make you high?

A: DFE is a central nervous system (CNS) depressant associated with a brief sensation of euphoria when inhaled. Prolonged or excessive use is associated with toxicity, and abrupt cessation can induce withdrawal.

Q: What happens if you accidentally inhale air duster?

A: When someone inhales air duster, it causes a depression of oxygen levels as the fumes go into the lungs and then the central nervous system. This can make it impossible for the person to breathe; therefore, they suffocate. Also possible is something called sudden sniffing death.

Q: Is difluoroethane a carcinogen?

A: 1 ,l -Difluoroethane is practically non-toxic following acute or chronic inhalation exposures. It is not a developmental or reproductive toxicant in rat studies and is negative for cancer in a two year rat inhalation study. It is not mutagenic in a in vitro bacterial reverse mutation assay and shows some weak clastogenicity in an in vitro human lymphocyte chromosome aberration test, but further evaluation of its ability to cause chromosome damage in and in vivo micronucleus test was negative. There is evidence that 1,1-difluoroethane can cause cardiac effects is some species, most notably heart arrhythmia in the dog.

Q: What is difluoroethane made of?

A: 1,1-Difluoroethane is a synthetic substance that is produced by the mercury-catalyzed addition of hydrogen fluoride to acetylene: HCCH + 2 HF → CH3CHF. The intermediate in this process is vinyl fluoride (C2H3F), the monomeric precursor to polyvinyl fluoride.

Q: Do people inhale difluoroethane?

A: It is a colorless, odorless, and extremely flammable gas. DFE can also cause frostbite on contact [1]. Spray propellants such as DFE, propane, and butane are sometimes misused, especially among young people in many countries, who report that inhaling them can induce euphoria and elation.

Q: Where do you get difluoroethane?

A: 1,1-difluoroethane (DFE) is a colorless, odorless gas used as a refrigerant chemical component of canned air which is commonly used to remove dust from computer keyboards and other electronics. This highly toxic chemical is found in products such as Dust-OffTM.

Q: How cold is difluoroethane?

A: Difluoroethane normally boils at -25°C (-13°F), but under ~6 atm (6 bar, 600 kpa) it is a liquid at room temperature. The gas also cools off slightly due to the Joule-Thompson effect of fluid expansion through a throttled valve.

Q: Is difluoroethane bad for the environment?

A: While not an ozone-depleting gas, difluoroethane is a greenhouse gas. It has a Global Warming Potential (GWP) of 140, according to the EPA, meaning one pound of difluoroethane is the equivalent of 140 pounds of carbon dioxide when it comes to global warming.

Q: Is difluoroethane toxic to dogs?

A: HFC-152a has low acute inhalation toxicity, with a 4-hour rat ALC of 383,000 ppm. As with most HFCs, HFC-152a has the potential to produce cardiac sensitisation in dogs challenged simultaneously with high exposure concentrations (150,000 ppm) and high doses of exogenous epinephrine.

Q: What are the properties of difluoroethane?

A: 1,1-Difluoroethane is colorless, odorless gas shipped as a liquefied gas under its vapor pressure. Contact with the liquid can cause frostbite. It is easily ignited. Its vapors are heavier than air and a flame can travel back to the source of leak very easily.

Q: Is Difluoromethane safe?

A: Uses advised against Consumer use. Flammable gas Category 1 H220: Extremely flammable gas. Gases under pressure Liquefied gas H280: Contains gas under pressure; may explode if heated. Hazard Statement(s): H220: Extremely flammable gas.

Q: How do you huff difluoroethane?

A: Bagging requires spraying the toxin in a bag and inhaling. Huffing entails soaking a rag with the chemical and inhaling. According to the National Institutes of Health, huffed difluoroethane has caused adverse effects including cardiomyopathy, angioedema, respiratory stridor, and loss of consciousness.

Q: What should you do if you inhale difluoroethane?

A: Seek medical attention. attention. breathing has stopped and CPR if heart action has stopped. overexposure, as pulmonary edema may be delayed.

Q: Is difluoroethane safe to inhale?

A: Air dusters can contain various ingredients, including some dangerous substances. They may contain dangerous ingredients that can cause side effects if a person inhales them, such as : difluoroethane, which can cause heart issues and loss of consciousness.

Q: Is difluoroethane a freon?

A: 1,1-difluoroethane (DFE; also known as HFC-152a and Freon® 152a) is a chlorofluorocarbon substitute that is used as a propellant in aerosol sprays and gas dusters. It is a colorless, odorless, and extremely flammable gas.

Q: Is difluoroethane a Pfas?

A: Currently, cosmetic products rely on hydrofluorocarbons (HFCs)-which are not PFAS-as aerosol propellants, in particular HFC-152a (1,1-Difluoroethane).
As one of the leading difluoroethane manufacturers and suppliers in China, we warmly welcome you to buy high-grade difluoroethane made in China here from our factory. All chemical products are with high quality and competitive price.

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